配体保护下的Au_(20)团簇吸附和活化CO的理论研究

用密度泛函理论方法计算了CO分子吸附在有机配体聚乙烯吡咯烷酮poly(N-vinyl-2-pyrrolidone)(PVP)保护下的Au20团簇上的稳定构型的结构和性质。配体PVP通过物理吸附主要作用于Au20团簇的顶点位置。与Au20比较,配体的存在有利于CO的吸附和活化,其根本原因是PVP和CO在Au20表面分别作为供电子和吸电子基团产生的协同效应。中性及阴离子Au20团簇对配体和CO的吸附强度不同,前者对PVP吸附作用较强,后者对CO的吸附和活化作用较强。     

广义Stokes方程的完全边界积分表示式及其在求解N-S方程中的应用

为了分解N-S方程组各变量相互偶合,本文采用Peaceman-Rachford算子分裂法,将时间相依的N-S方程组分解成不存在上述偶合特性的线性和非线性的子问题。线性子问题具有广义Stokes方程类型。本文采用多重互易法,即采用多阶拉普拉斯算子基本解逐步变换,将其解表示成完全边界积分形式,从而使问题的计算维数降低一维。广义Stokes方程的算例以及二维圆柱在剪切流中的Stokes绕流解,都表明多重互易算法具有高效特点,而且后者与文[3]解析解吻合得非常好。     

CHARACTERIZATIONS AND RELATIONSHIPS BETWEEN OUTDOOR AND INDOOR BIOAEROSOLS IN AN OFFICE BUILDING

1.IntroductionBioaerosolsaremicroorganismsorparticles,gases,vapors,orfragmentsofbiologicalorigin(i.e.,aliveorreleasedfromalivingorganism)thatexistintheair.Bioaerosolsareeverywhereintheenvironment.Underfavorableconditions,bioaerosolsareabletogrowandpropagateonavarietyofbuildingmaterialsandindoorsurfaces,causingindoorairpollution.Therefore,owingtotheirubiquitouspresenceinnature,bioaerosolsasapollutionsourcearealmostinevitableinarangeofenclosedenvironmentsandincommunityair(Kodama&McGee,1986;Lig…     

微加速度传感器的结构刚度分析新法

微传感器结构刚度是优化传感器结构尺寸、研究传感器动态响应特性的一个重要参数．目前多采用有限元分析获取这一参数,但该方法难于给出一个物理思想比较明确的解析表达式．针对自主开发设计的一种具有复杂微结构的加速度传感器,提出综合运用力法和能量法原理求解其主轴刚度,并通过仿真分析验证了理论推导．理论计算与仿真分析的结果有较好的一致性．该方法可推广应用于具有对称、静不定微结构的加速度传感器的刚度分析．     

INTERACTION OF ELECTRIC CHARGES IN A PIEZOELECTRIC WITH RIGID EXTERNAL CRACKS

IntroductionRecently much attention has been paid to Green’s functions[1 -7]for anisotropic mediabecause of their important applications in boundary element methods used widely inengineering analysis. Generally speaking, it is relatively easy to obtain G…     

Experimental and FEM study of windshield subjected to high speed bird impact

Both experimental and finite element model (FEM) results are presented for the dynamic strength behavior of windshield subjected to bird impact. The experimental data taken from a series of high speed photographs are compared with the numerical results predicted by using FEM in which the windshield was modeled entirely with solid elements and the bird body was approximately simulated by an elastic-plastic material with failure element behavior. Effective plastic strain and element pressure were adopted as the failure criteria and once the pressure or the effective plastic strain of an element reached the critical value, the element would lose the tensile resistance capability completely. The deflection and stress distribution in the windshield were obtained. It is shown that the result from the finite element analysis agrees with those from the full-scale bird impact test. The project supported by the National Natural Science Foundation of China (10272011)     

J．M．Dancan反转应力法的探讨

作者从近年来实际应用有限元法模拟地下工程开挖过程时发现的问题入手，讨论了Ｊ．Ｍ．Ｄａｎ－ｃａｎ反转应力法存在的缺陷．并进一步从理论上分析了Ｊ．Ｍ．Ｄａｎｃａｎ法出现问题的特征和条件．最后给出了一种可替代Ｊ．Ｍ．Ｄａｎｃａｎ反转应力释放法的直接积分法．     

单色光束的衍射度

受近期Gawhary和Severini在Opt.Lett.33,1360(2008)一文中引入的光束近轴度的启发,定义了一个独立于光束近轴度的衍射度参数来描述单色光束的衍射扩散程度,所定义的衍射度只依赖于光束的角谱分布,并可以定量比较不同光束的衍射扩散程度.     

一种异步非正交跳频网台盲分选方法

提出了一种新体制跳频网台盲分选方法,针对跳频通信异步非正交组网方式,将基于最大信噪比算法的盲源分离技术应用于跳频网台分选。建立了跳频网台盲分选仿真数学模型并进行了多跳频网台分选仿真。仿真结果验证了盲源分离技术应用在跳频网台分选中的可行性和有效性,得出了跳频网台盲分选方法对异步非正交组网方式的分选性能。